Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group.

نویسندگان

  • Luo-Qiang Zhang
  • Shiping Yang
  • Xiaolei Huang
  • Jingsong You
  • Feijie Song
چکیده

A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol.

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عنوان ژورنال:
  • Chemical communications

دوره 49 78  شماره 

صفحات  -

تاریخ انتشار 2013